Condition of disharge sulfat anions on anode

[Nimmull]

Yes in russia. If i have russian passport with a mutant chiken(two head).

[Nimmull]

What you think about sulfuric angidride? This substance is not conducting current because moleculas create dimers like a HF. May be it possible soluble some substance in sulfuric angidride to enchance it's conductivity?

[ChenBeier]

You mean SO₃? Sulfur trioxide, Sulfuric anhydride ?
Probably yes. Normal sulfate will convert to disulfate, trisulfate,etc.

SO₄ 2- + SO₃ => S₂O₇ 2-
S₂O₇ 2- + SO₃ => S₃O₁₀ 2-
And so one gets ( SO₄ * n SO₃) 2- , this should be conductive

[Nimmull]

Yes sulfuric anhydride is a SO₃. May be sulfate will not soluble in SO₃ but a bit of waterless sulfuric acid will soluble. It's a nice idea hyperoleum a bit of H₂SO₄ solubled in SO₃.

[Nimmull]

do you go online when it’s night, are you in America?
Let's continue our discussion.
Let's imagine that we have an electrolyzer, in the cathode space [emim]CH₃SO₃ it is followed by an intermediate space with sulfuric acid, it is separated by a porous partition from the cathode space. then comes the anode space, it contains SO₃ * nH₂SO₄, it is also separated by a porous partition from the intermediate space. We will dissolve the sulfate in the electrolyte of the cathode space and begin electrolysis.
what do we get at the anode SO₃ + O or (S₂O₈)₂-?

[Nimmull]

Intermediate space is used for protect cathode electrolyte from sulfuric anhydride. Because sulfuric angidride will kill any organical compounds.

[ChenBeier]

No I am in Europe.

I have no idea what products you get in your device.
Maybe you have to do tests and experiments.
One concern is the water free sulfuric acid. It is very hygroscopic and will absorb water from the humidity in the air.

[Nimmull]

In russian internet i not found books about this processes. Experiment will show the truth.