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Which alcohols decolourise?

Posted: Tue Oct 17, 2023 3:08 pm
by bohojekek
I know that for alkaline potassium permanganate, solution turns either brown (adding primary alcohol) or green (secondary alcohol) or remains purple (tertiary alcohol). Not as sure about acidic. When will acidic potassium permanganate decolourise and what are the other colour changes possible?

Re: Which alcohols decolourise?

Posted: Tue Oct 17, 2023 3:28 pm
by ChenBeier
Acidic Permanganate decolorize to Mn 2+. colorless slight pink. Some end with brown MnO2 between. The alcohol will be destroyed to CO2 and water.

Re: Which alcohols decolourise?

Posted: Tue Oct 17, 2023 3:33 pm
by bohojekek
Thank you, so this occurs for all alcohols other than tertiary?

Re: Which alcohols decolourise?

Posted: Tue Oct 17, 2023 3:44 pm
by ChenBeier
Also tertiary. Result is CO2 and water.

Re: Which alcohols decolourise?

Posted: Mon Nov 13, 2023 7:25 pm
by taniyuki
In the case of a primary or secondary alcohol, the orange solution turns green. With a tertiary alcohol there is no colour change.

Re: Which alcohols decolourise?

Posted: Tue Nov 14, 2023 5:43 am
by ChenBeier
It was asked for acidic not alcaline. Your answer is wrong and it's already given above. Read more carefully before answering.