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Balance the Reaction

Posted: Sun Apr 17, 2022 10:32 pm
by Abuzar Shahid
I'm working on preparing CuS particles and having hard time balancing the reaction of:
Cu(CH3COO).2H2O + Na2S2O3.5H2O

Re: Balance the Reaction

Posted: Mon Apr 18, 2022 3:04 am
by ChenBeier
Disproportion of thiosulfate

5H2O + S2O3 2- => 2 SO4 2- + 10 H+ + 8 e- Oxidation
6 H+ + S2O3 2- + 8 e- => 2 S 2- + 3 H2O Reduktion

2 H2O + 2 S2O3 2- => 2 SO4 2- + 2 S 2- + 4 H+ sum
H2O + S2O3 2- => SO4 2- + S 2- + 2 H+ divided by 2

The S 2- react with the Cu 2+ to CuS

Re: Balance the Reaction

Posted: Mon Apr 18, 2022 10:47 am
by Abuzar Shahid
will me reaction be affected if I use copper acetate dihydrate instead of copper acetate monohydrate

Re: Balance the Reaction

Posted: Mon Apr 18, 2022 10:51 am
by ChenBeier
No. Its All spectator ions.

Re: Balance the Reaction

Posted: Mon Apr 18, 2022 11:16 am
by Abuzar Shahid
Thank u so much. i was getting lesser product with dihydrate. thanks again :)

Re: Balance the Reaction

Posted: Mon Apr 18, 2022 12:12 pm
by ChenBeier
Of course you have to do the right calculation. 1 g mono Hydrate is not the same like 1 g dihydrate. You have to convert the mass via the moles.