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Percentage concentration to molar concentration

Posted: Wed Mar 30, 2022 8:00 am
by ferrouspatrick
Hi there!

I'm having trouble calculating the molar concentration of 70% isopropanol (2-propanol). Said 70% is by weight. I'd really appreciate some help since i don't know how to calculate this.

Re: Percentage concentration to molar concentration

Posted: Wed Mar 30, 2022 8:08 am
by ChenBeier
Are you sure its by weight. Alcohol is normaly calculated by volume. Nevertheless weight means 1 kg contain 700 g Isopropanol = 70 % w.w.
If it is by volume its 700 ml in 1 l alcohol = 70% v.v.
To convert you need the specific gravity.

Re: Percentage concentration to molar concentration

Posted: Wed Mar 30, 2022 8:16 am
by ferrouspatrick
Yeah, im sorry, i made a mistake. The actual concentration is 99.7% v-v, and the density is 0.786 g/cm3.

Re: Percentage concentration to molar concentration

Posted: Wed Mar 30, 2022 8:48 am
by ChenBeier
So 1 l has a weight of 786 g, 99,7% v.v is 997 ml 100% alcohol. 3 ml = 3 g is water.. So the concentration is (786 g -3 g) / 0,997 l = 785,36 g/ l. The molar mass is 60 g/mol what gives a molarity of 13,08 mol/l.

Re: Percentage concentration to molar concentration

Posted: Wed Mar 30, 2022 11:56 am
by ferrouspatrick
Thank you very much! That helps a lot.