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equivalent weight, molecular weight and formula for the unknown acid

Posted: Thu Mar 10, 2022 10:58 am
by Dhamnekar Winod
A solution of 3.15 g of an acid dissolved in 100 g of benzene boils at 80.985 ℃ ( the boiling point of pure benzene is 80.099 ℃). A 0.2145- g sample of the same acid requires 45.22 ml of a 0.1054 M of sodium hydroxide(NaOH) solution for complete neutralization. Complete combustion of 1.004 g of the acid produced 0.9817 g of CO2 and 0.2007 g of H2O.

(a) Calculate the equivalent weight of the acid.

(b)Calculate the molecular weight and molecular formula of the acid.

(c)Write an electron dot formula for the acid.

I am working on this question. Any chemistry help will be accepted.

Re: equivalent weight, molecular weight and formula for the unknown acid

Posted: Thu Mar 10, 2022 12:25 pm
by ChenBeier
Answer is oxalic acid HOOC-COOH. Molar mass 90 g/ mol obtained by the boiling point difference of solution and solvent. Need ebullioscopic constant of Benzene 2,53 Kg K/mol for calculation

Combastion analysis gives ratio of C and H 1:1.

Neutralisation gives 4,766 mmol acid with the given mass it will be 45 g/ mol what means the acidity is the half of 90 g/ mol.

Re: equivalent weight, molecular weight and formula for the unknown acid

Posted: Tue Mar 15, 2022 7:52 am
by Dhamnekar Winod
Correct answer.