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Could you please help me out at this reaction ?
Posted: Sun Dec 23, 2018 9:28 am
by doctorx
As2S3 +Ca(HCO3)2 + H2O = ?????
As2S3 and Ca(HCO3)2 are as mixed powders and are going to solve in water
Thank you
Posted: Sun Dec 23, 2018 12:12 pm
by ChenBeier
Arsenic sulfide is not solouble and Calciumhydrogencarbonate is not existing as a powder. It can only made by adding carbondioxide in excess to a solution of calciumcarbonate or calcium hydroxide.
So there will be not much reaction.
Therotically calcium thioarsenite Ca3(AsSxOy)2 x =0,1,2,3; y = 3-x can be a result.
Posted: Fri Dec 28, 2018 8:57 am
by doctorx
Thank you so much
Actually I made a mistake
It is CaCO3 (Lime) not Ca(HCO3)2.
In fact it is a big health issue in my region
I am a doctor and in my region this compond is widely used.
It consist of 6 part CaCO3 and one part As2S3 powder mixed together.
at time of use ( for body hair removal ) they add water and make a paste of it and put it on skin.
The powder mixture has no odor at all but when water added a strong odor of H2S fills the space, so I think in presence of CaCO3, air CO2 and H2O , As2S3 may has a reaction resulting in H2S production and probably some arsenic component soluble in water which can be toxic.
I need to know what is the reaction and end products as well as the balanced equation
your help would be great for a lot of people.
Thanks again
Posted: Fri Dec 28, 2018 9:12 am
by ChenBeier
The problem is that arsenic compound is used. It will be the root course.
https://en.wikipedia.org/wiki/Arsenic_trisulfide
The result of the reaction I had given
Therotically calcium thioarsenite Ca
3(AsSxOy)
2 x =0,1,2,3; y = 3-x can be a result.
3 CaCO
3 + As
2S
3 => Ca
3(As
2S
3O
3) + 3 CO
2
Sulfur and Oxygen can be exchanged what guides to the smell of H
2S by water
Ca
3(AsS
3)
2 until Ca(AsO
3)
2 is possible.
The arsenic compunds with oxygen are more solouble and will penetrate through the skin and poisson the body.
Stopp using arsenic compounds for cosmetic purpose!!!!!
Posted: Fri Dec 28, 2018 9:45 am
by doctorx
Thank you so much for your great help.
I really appreciate.
Posted: Fri Dec 28, 2018 9:47 am
by ChenBeier
You wellcome. By the way which country does it happen.
Posted: Fri Dec 28, 2018 9:22 pm
by doctorx
Iran
It s an Islamic tradition
Posted: Sat Dec 29, 2018 5:32 am
by ChenBeier
Oh, I see. I think they should not give up the traditions, but use something else instead of arsenic.
Posted: Sun Dec 30, 2018 7:50 am
by doctorx
We as doctors recommend new Arsenic free products but they insist that Arsenic has good health effect for body !!!
We have to inform the superstitious people.
They believe inhaling that bad odor fights lung cancer.
Our health ministry also forbided Arsenic for cosmetic use.
Posted: Sun Dec 30, 2018 12:32 pm
by ChenBeier
Arsenic compounds should not sold to normal people. Forced by authorities.
Posted: Sun Jan 06, 2019 4:29 pm
by doctorx
of course
Posted: Wed Jan 09, 2019 9:49 am
by sepetrified
As
2S
3 and Ca(HCO
3)
2 old post about the SizeGenetics are as mixed powders and are going to solve in water
Posted: Wed Jan 09, 2019 11:02 am
by ChenBeier
it was the starting post
Ca(HCO3)2 is not existing as a powder