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Choosing proper Lewis acid

Posted: Thu May 10, 2018 10:55 am
by PyroMaster
So,which lewis acid to chose in adition of hydrogen sulfide to ketones
Eg. H2S+C3H6O=[(CH3)2CS]3+H2O
I have readen about TiCl4 but don't know if it's geometrical structure corresponds to this reaction.

Posted: Sat May 12, 2018 3:02 am
by ChenBeier

Posted: Sat May 12, 2018 6:50 am
by PyroMaster
Never thought about thionating agent,i will try with phosphorous pentasulfide as I can't acces lawessons reagent.It should work but with longer preparation time and lower yield.Thanks.