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Organic chemistry-alkene

Posted: Sat Jul 13, 2013 1:45 am
by popabiancamaria
Which alkene ozonolysis which forms a ketone and an aldehyde.And that alkene is obtained by dehydrating tertiary alcohol with molecular formula C5H12O...




Care este alchena care la ozonoliza formeaza o cetona si o aldehida si care se obtine prin deshidratarea alcoolului tertiar cu formula moleculara C5H12O?

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Re: Organic chemistry-alkene

Posted: Mon Jul 15, 2013 4:49 pm
by GrahamKemp
popabiancamaria wrote:Which alkene ozonolysis which forms a ketone and an aldehyde.And that alkene is obtained by dehydrating tertiary alcohol with molecular formula

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C5H12O
?
The only tertiary alcohol of that formula is 2-methyl-2-butanol.

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CH3CH2COH(CH3)2
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This dehydrates to produce 2-methyl-2-butene or 2-methyl-1-butene.

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CH3CH2COH(CH3)2 --> CH3CH=C(CH3)2 , CH2=C(CH3)CH2CH3 
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The former ozonolysises into ethanal and propanone

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CH3CH=C(CH3)2 + O3 --> CH3CHO + CH3COCH3 
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The later ozonolysises into methanal and butanone.

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CH2=C(CH3)CH2CH3 + O3 --> CH2O + CH3CH2COCH3
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