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how to show a double bond in an equation?

Posted: Wed Oct 12, 2011 2:40 pm
by swanmaid
O
CH3CH2C - Cl + 2NH3 > ?

Posted: Wed Oct 12, 2011 9:28 pm
by expert
Please write carefully what CH3CH2C - Cl is

CH3CH2Cl? CH3CH=CH-Cl ? Else?

showing a double bond in an equation

Posted: Fri Oct 14, 2011 2:45 pm
by swanmaid
expert,

You missed the question & the formula. The question is how to show/or illustrate a double bond in the posting. Sorry if this was not made clear.

My formula - O
CH3CH2C - Cl + 2NH3 > ?

How do I show the double bond between the 1st C and the O?


What you wrote - CH3CH2Cl? CH3CH=CH-Cl ?

The formulas are very different.

Posted: Sat Oct 15, 2011 2:39 pm
by expert
To draw the structures I recommend downloading software. There are free programs, and most higher level programs are available for free trial and discounts for students.
Check these links:
http://scistore.cambridgesoft.com/Scist ... rial=Trial
http://www.chemdoodle.com/free-trial/
http://super-chemistry.narod.ru/Structures.html

For simple situations like in your case there is no need putting oxygen atom above the carbon. You can write it like
CH3-C(O)-CH3 (acetone) or
CH3-CH2-CH=O or O=CH-C2H5 (both correct for propionaldehyde)

In your case, if you mean the double bond between O and C,

O
!!
CH3CH2C - Cl

then the structure doesn't make sense anyway. Carbon must have four bonds, not six like in your case. That’s why I asked you to provide the correct structure. Maybe you mean this?

...............O
...............!!
CH3CH2C - Cl

Better write it this way:

CH3-CH2-C(O)-Cl or simply CH3CH2C(O)Cl

In that case the reaction is

CH3CH2C(O)Cl + 2 NH3 = CH3CH2C(O)NH2 + NH4Cl

Posted: Sun Oct 16, 2011 10:55 am
by expert
I also recommend for more complex drawings to use these tools provided on this website:
http://www.webqc.org/chemicaltools.php (select one of visualization tools)
For example, I drew your reaction here using Marvin Sketch tool
Image