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Redox reactions
Posted: Sat Jul 24, 2021 5:48 am
by Dhamnekar Winod
How to answer all these following questions?
I am working on these questions. If you know the answers to these questions, you may post them. Why can't i paste the screenshot copied on clipboard here?
- electrontransfer reaction.png (51.96 KiB) Viewed 5103 times
Re: Redox reactions
Posted: Sat Jul 24, 2021 6:13 am
by ChenBeier
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For redox reaction use the redox pair law
a) S2O3 2- / S4O6 2- and I2/I-
2 S2O3 2- => S4O6 2-
Balance charge
2 S2O3 2- => S4O6 2- + 2e-
I2 => 2 I-
Balance charge
I2 + 2e- => 2 I-
Addition
2 S2O3 2- + I2=> S4O6 2- + 2 I-
Try the other by yourself.
Re: Redox reactions
Posted: Sun Jul 25, 2021 2:02 am
by Dhamnekar Winod
Answers to a), b) , C).
- RR123.png (29.1 KiB) Viewed 5077 times
Re: Redox reactions
Posted: Sun Jul 25, 2021 6:29 am
by ChenBeier
The final results are ok, I am wondering where the 2 H+ + 2e- comming from. Especially there is no acid in 1. and 2.
Fe 2+ => Fe 3+ + e- Oxidation
Ce 4+ +e - => Ce 3+ Reduction
Fe 2+ + Ce 4+ => Fe 3+ + Ce 3+ Addition
Sulfate is spectator ion
For completion multiply by 2 and add SO4 2-
2 FeSO4 + 2 Ce(SO4)2 => Fe2(SO4)3 + Ce2(SO4)3
Fe 2+ => Fe 3+ + e- Oxidation
HNO3 + 3 H+ + 3e- => 2 H2O + NO Reduction
Multiplikation of Oxidation by 3
3 Fe 2+ + 3 Fe 3+ + 3 e-
3 Fe 2+ + HNO3 + 3 H+ => 3 Fe 3+ + 2H2O + NO Addition
Also hier sulfate is spectator but can be added accordingly
6 FeSO4 + 2HNO3 + 3 H2SO4 => 3 Fe2(SO4)3 + 4 H2O + 2 NO
Re: Redox reactions
Posted: Wed Jul 28, 2021 12:32 am
by Dhamnekar Winod
Answers to d), e), f), g).
- RRdefg.png (36.97 KiB) Viewed 5025 times
Re: Redox reactions
Posted: Wed Jul 28, 2021 2:39 am
by ChenBeier
I dont understand how you develop the part equations. In e) for example you use OH- even the reaction takes place with HCl. With mathematics a lot can do even the final result is correct but generally its wrong.
To start like this
d) S 2- => S + 2 e- Oxidation
HNO3 + 3 H+ +3 e- => NO + 2 H2O Reduction
e) S 2- => S+ 2 e- Oxidation
Cr2O7 2- + 6 HCl + 8 H+ + 6 e- => 2 Cr 3+ + 7 H2O + 6 Cl- Reduction
f) Cl2 + 12 OH- => 2 ClO3- + 6 H2O + 10 e- Oxidation
Cl2 + 2 e- => 2 Cl- Reduction
g) Fe 2+ => Fe 3+ + e- Oxidation
O2 2- + 2H2O + 2 e- => 4 OH- Reduction
Re: Redox reactions
Posted: Wed Jul 28, 2021 8:29 am
by Dhamnekar Winod
In answer to e) , I used basic medium even though HCl is reactant. You said it is wrong. After using acidic medium, the answer is as follows:
- RRehij.png (20.52 KiB) Viewed 5011 times
The balanced net ionic equations for h), i), j) are as follows:
h)
\(Bi_2S_3 + 8HNO_3 \rightleftarrows 2Bi(NO_3)_3 + 2NO + 3S + 4H_2O\)
i)
\(H_3AsO_4 + 4Zn + 8HNO_3 \rightleftarrows AsH_3 + 4Zn(NO_3)_2 + 4H_2O\)
j)
\(2CrI_3 + 64NaOH + 27Cl_2 \rightleftarrows 2Na_2CrO_4 + 6NaIO_4 + 54NaCl + 32H_2O\)