Page 1 of 1

Phenyl Lithium Reaction

Posted: Tue Dec 19, 2023 9:34 am
by harshitbbaruah
I need an answer and explanation of the following reaction. The answer is option (a) but the book doesn't provide a mechanism.
Phli.jpg
Phli.jpg (341.97 KiB) Viewed 2826 times

Re: Phenyl Lithium Reaction

Posted: Tue Dec 19, 2023 9:55 am
by ChenBeier
Phenyllithium attack the CH2 group between the two Carbonylgroups. The Carbanion will push out the bromine and close the ring. This guide to product b first. With Hypoiodite it reduces b to product a by releaising acetate.